Strong intramolecular chromophore interactions in novel bis([60]fullerene)-oligoporphyrin nanoarrays

D. Bonifazi, F. Diederich,
Chem. Commun. (Cambridge, U. K.) 2002, 2178-2179
DOI: 10.1039/B206624F


Novel nanodimensional dyads were prepared by Bingel reaction of meso, meso-linked oligoporphyrin bis-malonates with C60. Distinct conformational effects were observed as a result of strong fullerene–porphyrin interactions, which also lead to efficient quenching of the porphyrin luminescence.

Comments are closed.